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绿色化学、有机化学、现代有机合成、金属有机化学

科研简介

主要从事绿色化学与有机功能分子材料的精准合成及其在光电转换、传感以及信息存储技术上的应用等研究。包括研究探索有机分子中惰性碳氢键、碳碳键的选择性活化与官能团化方法，开发绿色高效的催化体系，实现有机功能分子的定向、精准合成；同时，立足于解决功能材料在分子结构设计与功能调控方面存在的关键科学问题与技术需求，结合现代分析传感探测技术，研究有机分子传感及影像、有机发光与信息存储等功能材料与器件的可控合成与性能的调控，以期实现有机功能材料在微电子、生物医药、信息与通讯等高新技术领域应用瓶颈的突破。已在J. Am. Chem. Soc., Angew. Chem. Int. Ed.,  Org. Lett., Green Chem.等国内外重要学术刊物上已发表论文150余篇，授权发明专利20余项。

科研项目

目前主持国家自然科学基金5项，参加国家科技部重点基础发展研究计划1项。

社会兼职

中国化学会理事，江西省石油和化学工业协会副理事长，江西省石油学会副理事长，江西省应急管理学会副理事长

代表性论文及专利    

1. Metal-Free, Site-Selective C−H Fluorination of Heteroarenes under Visible Light. Cheng Huang; Chang-Ming You; Yu-Shu Qin; Rui-Nan Ci; Peng Xiao; Sheng Tang; Bin Liu; Zhenhong Wei; Li-Zhu Wu; Hu Cai.  CCS Chemistry , 2024, 1-17.

2.  Direct C(sp3)-H Arylation of Unprotected Benzyl Anilines and Alkylarenes by Organocatalysis under Visible Light. Huang, Cheng; Xiao, Peng; Ye, Zhong-Ming; Wang, Chen-Lu; Kang, Chen; Tang, Sheng; Wei, Zhenhong; Cai, Hu.  Organic Letters,  2024,  26(1) , 304-309.

3. Electrochemical Decarboxylative Alkoxy-alkoxycarbonylation of Alkenes. Lu, Meiqun; Chen, Kailun; Wu, Tao; Cai, Hu.  Organic Letters,  2024,  26(1) , 188-192.

4. An electrochemical method for deborylative selenylation of arylboronic acids under metal- and oxidant-free conditions. Fu, Zhengjiang; Yin, Jian; He, Dongdong; Yi, Xuezheng; Guo, Shengmei; Cai, Hu.  Green Chemistry , 2022,  24(1) , 130-135.

5. The Role of Fluorine-Substituted Positions on the Phase Transition in Organic-Inorganic Hybrid Perovskite Compounds. Rao, Wenjun; Li, Mingli; You, Xiuli; Wei, Zhenhong ; Zhang, Mengxia; Wang, Lingyu; Cai, Hu.  Inorganic Chemistry,  2021,  60(19) , 14706-14712.

6. High-Temperature Switchable Nonlinear Optical and Dielectric Material Revealed by Molecular Modification. Xie, Yongfa; Zheng, Jingjing; Zheng, Kuangqi; Liu, Qing; Duan, Jie; Chen, Wei; Shao, Shuke; Cai, Hu.  Chemistry of Materials, 2021,  33(9) , 3081-3086.

7. Environmentally sustainable production and application of acyl phosphates. Guo, Shengmei; Li, Sen; Yan, Wenjie; Liang, Zhibin; Fu, Zhengjiang; Cai, Hu.  Green Chemistry, 2020,  22(21) , 7343-7347.

8. DMSO/t-BuONa/O₂-Mediated Aerobic Dehydrogenation of Saturated N-Heterocycles. Yang, Ruchun; Yue, Shusheng; Tan, Wei; Xie, Yongfa; Cai, Hu.  Journal of Organic Chemistry,  2020,  85(11) , 7501-7509.

9. An electrochemical method for deborylative seleno/thiocyanation of arylboronic acids under catalyst- and oxidant-free conditions. He, Dongdong; Yao, Jiaojiao; Ma, Boling; Wei, Jinghao; Hao, Guangguo; Tuo, Xun; Guo, Shengmei; Fu, Zhengjiang; Cai, Hu.  Green Chemistry,  2020,  22(5) , 1559-1564.

10. Rational design of ceramic-like molecular ferroelectric by quasi-spherical theory. Wei, Zhen-Hong ; Jiang, Zhen-Tao; Zhang, Xiu-Xiu; Li, Ming-Li; Tang, Yuan-Yuan; Chen, Xiao-Gang; Cai, Hu; Xiong, Ren-Gen.  Journal of the American Chemical Society, 2020,  142(4), 1995-2000.